Cyclohexanone → Cyclohexanone

HRID 426586

反応式

HRID 426586 の反応式
[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1>O>[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:1]1(=[C:2]2[CH2:3][CH2:4][CH2:5][CH2:6][C:1]2=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

参加物

4

反応物 1

HCID 7967Cyclohexanone

生成物 2

HCID 7967CyclohexanoneHCID 13892Bicyclohexyliden-2-one

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Using the equipment from Example 15, 1500 ml cyclohexanone was charged to the flask with 100 g aluminum oxycarbonate. The flask was heated to an initial boiling point of 142 degrees C. Water evolved quickly and the temperature rose to 200 degrees C. in three hours. The fluid was decanted and distilled yielding unreacted cyclohexanone along with cyclohexylidene cyclohexanone and the higher condensation product C18H26O believed to be dicyclohexylidene cyclohexanone.

後処理

  1. temperatureThe flask was heated to an initial boiling point of 142 degrees C
  2. customrose to 200 degrees C
  3. customThe fluid was decanted
  4. distillationdistilled

出典と根拠

ORDレコード
ord-91875b6c0c984e0fb4f672eb1530f989
出典データセット
uspto-grants-1979_10
特許番号
US04170609

関連ノート

読み込み中…