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HRID 428232作成日：2026年10月25日

Ethyl 2-[5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphth-2-yl]benzoate → 2-(5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphth-2-yl)benzylalcohol

https://huagongshe.com/reaction/428232

反応式

関与物質

役割名称HCID仕込み量
反応物Ethyl 2-[5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphth-2-yl]benzoateHCID 18357939—
反応物DiisobutylaluminumhydrideHCID 21225700—
生成物2-(5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphth-2-yl)benzylalcoholHCID 18357953—

反応手順

Employing the same general procedure as used for the preparation of 3-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphth-2-yl)but-2(Z)-en-1-ol (Compound C), but instead using 420 mgs (1.25 mmols) ethyl 2-[5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphth-2yl]benzoate (Compound H) and 6 mmols of diisobutylaluminiumhydride the title compound was obtained as a white solid.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US06313163B1
出典データセットuspto-grants-2001_11
ORD IDord-4b95b2c90ddd4295b3b5c3a4d713da34
出典メモuspto-grants-2001_11