関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 反応物 | Diallylamine | HCID 31279 | — |
| 反応物 | 3-Fluoro-4-nitroaniline | HCID 75401 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | N,N-diallyl-6-nitro-1,3-benzenediamine | HCID 22251449 | 98.6% |
反応手順
A mixture of 3-fluoro-4-nitroaniline (1.56 g, 10 mmol), 1-methylpyrolidinone (10 mL), diallylamine (1.94 g, 20 mmol) and potassium carbonate (1.38 g, 10 mmol) was heated to 115-125 ° C. for 9.5 h. The mixture was diluted with water, and extracted with ethyl ether. The combined extracts were washed with water, washed with saturated brine solution, and dried over magnesium sulfate. The extract was concentrated to give N,N-diallyl-6-nitro-1,3-benzenediamine as an orange oil (2.3 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06313348B1 |
|---|
| 出典データセット | uspto-grants-2001_11 |
|---|
| ORD ID | ord-28b93eaa005f48068dd8c1543a6e8d6e |
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| 出典メモ | uspto-grants-2001_11 |
|---|
