Naphthalic anhydride → HCID 178524212、化合物

HRID 429530

反応式

HRID 429530 の反応式
[C:1]12[C:14](=[O:15])[O:13][C:11](=[O:12])[C:9]3=[C:10]1[C:5](=[CH:6][CH:7]=[CH:8]3)[CH:4]=[CH:3][CH:2]=2.P([O-])([O-])([O-])=O.[OH:21][NH3+:22].O[NH3+].O[NH3+]>O>[OH:21][N:22]=[C:14]([C:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][C:9]=2[C:11]([OH:13])=[O:12])[CH:4]=[CH:3][CH:2]=1)[OH:15]

参加物

4

反応物 2

HCID 6693Naphthalic anhydrideHCID 10176537Hydroxylammonium phosphate (3:1)

生成物 1

HCID 178524212HCID 178524212、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

1.98 g (10.0 mmol) of 1,8-naphthalenedicarboxylic anhydride and 0.985 g (5.00 mmol) of hydroxylammonium phosphate were reacted with 2 ml of water analogously to Example 7 for 6 hours at a bath temperature of 130° C. Following cooling, the pale brown reaction mixture was digested with water, and the solid was filtered off with suction and dried. The yield was 1.89 g (89%).

後処理

  1. temperatureFollowing cooling
  2. filtrationthe solid was filtered off with suction
  3. customdried

出典と根拠

ORDレコード
ord-d550999d032d4d73aaefed2123068ef6
出典データセット
uspto-grants-2001_11
特許番号
US06316639B1

関連ノート

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