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Methylamine → 10-(Hydroxymethyl)-9-((methylimino)methyl)anthracene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methylamine | HCID 6329 | — |
| 反応物 | 10-(Hydroxymethyl)anthracene-9-carbaldehyde | HCID 3765036 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 10-(Hydroxymethyl)-9-((methylimino)methyl)anthracene | HCID 22662200 | — |
反応手順
10-(hydroxymethyl)-9-anthraldehyde (3.00 g, 12.7 mmol) was added to 50 mL of a saturated solution of methylamine in methanol and stirred at room temperature for 2 h. The solvent and excess methylamine was removed under reduced pressure to afford the imine as a bright yellow powder (quant); 1H NMR (300.13 MHz, DMSO-d6) δ3.35 (s, 3H), 5.51 (s, 2H), 7.61 (m, 4H), 8.55 (m, 4H), 9.48 (s, 1H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06319540B1 |
| 出典データセット | uspto-grants-2001_11 |
| ORD ID | ord-8bc12dc99a0047928b869c8fed4a9718 |
| 出典メモ | uspto-grants-2001_11 |