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HRID 43037作成日:2026年10月25日

Toluene → 2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester, polymer with butyl 2-propenoate

https://huagongshe.com/reaction/43037

反応式

関与物質

役割名称HCID仕込み量
反応物TolueneHCID 1140—
反応物Glycidyl methacrylateHCID 7837—
反応物1-DodecanethiolHCID 8195—
反応物Butyl AcrylateHCID 8846—
溶媒Toluene ethanolHCID 21863594—
生成物2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester, polymer with butyl 2-propenoateHCID 21915774—

反応手順

50 g of N-butyl acrylate (product of Nippon Shokubai Co., Ltd.), 50 g of glycidyl methacrylate (product of Mitsubishi Gas Chemical Company Inc.), 3 g of lauryl mercaptan (product of Wako Pure Chemical Industries Ltd.), and 100 g of toluene were placed in a 1 L-separable flask equipped with a stirrer, a condenser, a thermometer, and a nitrogen gas-introducing inlet, and mixed to give a monomer mixture solution. The obtained monomer mixture solution was bubbled with nitrogen gas for 20 minutes to remove the dissolved oxygen. Thereafter, the system in the separable flask was replaced with nitrogen gas, and the temperature inside the separable flask was raised to a reflux temperature under stirring. Next, polymerization was performed in the same manner as that in Synthesis Example 6 to provide a toluene/ethanol solution of a poly(glycidyl methacrylate/n-butyl acrylate) copolymer (B8) (number-average molecular weight of 3,000 as converted to polystyrene, epoxide equivalent of 284) as a curable compound having at least two glycidyl groups.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US08536242B2
出典データセットuspto-grants-2013_09
ORD IDord-818b5de95ec84349a493cb973336f9b6
出典メモuspto-grants-2013_09