Bis(2-hydroxyethyl) terephthalate → Bis(2-hydroxyethyl) benzene-1,4-dicarboxylate;1-dichlorophosphoryloxyethane

HRID 430398

反応式

HRID 430398 の反応式
[C:1]([O:15][CH2:16][CH2:17][OH:18])(=[O:14])[C:2]1[CH:13]=[CH:12][C:5]([C:6]([O:8][CH2:9][CH2:10][OH:11])=[O:7])=[CH:4][CH:3]=1.[P:19]([Cl:25])([Cl:24])(=[O:23])[O:20][CH2:21][CH3:22]>CN(C)C1C=CN=CC=1.C(Cl)Cl>[C:6]([O:8][CH2:9][CH2:10][OH:11])(=[O:7])[C:5]1[CH:4]=[CH:3][C:2]([C:1]([O:15][CH2:16][CH2:17][OH:18])=[O:14])=[CH:13][CH:12]=1.[P:19]([Cl:25])([Cl:24])(=[O:23])[O:20][CH2:21][CH3:22]

参加物

5

反応物 2

HCID 13739Bis(2-hydroxyethyl) terephthalateHCID 15158Ethyl dichlorophosphate

生成物 1

HCID 131723001Bis(2-hydroxyethyl) benzene-1,4-dicarboxylate;1-dichlorophosphoryloxyethane

試薬・触媒・溶媒 2

HCID 142844-(Dimethylamino)pyridine触媒HCID 6344Dichloromethane溶媒2 回

反応条件

温度
-40 °C

実験手順

Under an argon stream, 10 g of 1,4-bis(hydroxyethyl) terephthalate (BHET) prepared as described above in Example 1, 9.61 g of 4-dimethylaminopyridine (DMAP), and 70 mL of methylene chloride were placed in a 250 mL flask equipped with a funnel. The solution in the flask was cooled down to −40° C. with stirring, and a solution of 5.13 g of ethyl phosphorodichloridate (EOP) (distilled before use) in 20 mL of methylene chloride was added dropwise through the funnel. After addition was complete, the mixture was stirred at room temperature for four hours to form the homopolymer BHET-EOP.

後処理

  1. customwere placed in a 250 mL flask
  2. customequipped with a funnel
  3. additionAfter addition
  4. stirringthe mixture was stirred at room temperature for four hours

出典と根拠

ORDレコード
ord-6924e253ced34f6d8223e02e166064be
出典データセット
uspto-grants-2001_11
特許番号
US06322797B1

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