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HRID 43042作成日:2026年10月26日

Acrylic Acid → Phenoxyethyl acrylate methyl methacrylate acrylic acid

https://huagongshe.com/reaction/43042

反応式

関与物質

役割名称HCID仕込み量
反応物Acrylic AcidHCID 6581—
反応物Methyl MethacrylateHCID 6658—
反応物Phenoxyethyl acrylateHCID 39485—
反応物1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 75763—
溶媒IsopropanolHCID 3776—
溶媒Methyl Ethyl KetoneHCID 6569—
生成物Phenoxyethyl acrylate methyl methacrylate acrylic acidHCID 86634647—

反応条件

温度75 °C

反応手順

360.0 g of methyl ethyl ketone was placed in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of V-601 (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of V-601 in 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 in 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (in a ratio of 50/45/5 by mass) was obtained.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US08536246B2
出典データセットuspto-grants-2013_09
ORD IDord-f004e0d262a14ed7a044fb9b23872c59
出典メモuspto-grants-2013_09