関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Acrylic Acid | HCID 6581 | — |
| 反応物 | Methyl Methacrylate | HCID 6658 | — |
| 反応物 | Phenoxyethyl acrylate | HCID 39485 | — |
| 反応物 | 1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate) | HCID 75763 | — |
| 溶媒 | Isopropanol | HCID 3776 | — |
| 溶媒 | Methyl Ethyl Ketone | HCID 6569 | — |
| 生成物 | Phenoxyethyl acrylate methyl methacrylate acrylic acid | HCID 86634647 | — |
反応手順
360.0 g of methyl ethyl ketone was placed in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of V-601 (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of V-601 in 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 in 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (in a ratio of 50/45/5 by mass) was obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US08536246B2 |
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| 出典データセット | uspto-grants-2013_09 |
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| ORD ID | ord-f004e0d262a14ed7a044fb9b23872c59 |
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| 出典メモ | uspto-grants-2013_09 |
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