Acetic Anhydride → 1,3,5-Adamantanetriol
反応式
[OH:1][C:2]12[CH2:11][CH:6]3[CH2:7][CH:8]([CH2:10][C:4]([OH:12])([CH2:5]3)[CH2:3]1)[CH2:9]2.C(OC(=O)C)(=[O:15])C.OC12CC3CC(CC(C3)C1)C2>>[OH:1][C:2]12[CH2:11][C:6]3([OH:15])[CH2:7][CH:8]([CH2:10][C:4]([OH:12])([CH2:5]3)[CH2:3]1)[CH2:9]2参加物
4
実験手順
One mol of 1,3-dihydroxyadamantane was stirred in an acetic acid-acetic anhydride solution of CrO3, oxidizing agent, with heating. After carrying out the reaction for 8 hours, the reaction solution was neutralized to obtain a mixture of polyhydroxylated compounds of hydroxyadamantane. This mixture was partitioned by high performance liquid chromatography to obtain 1,3,5-trihydroxyadamantane.
後処理
- temperaturewith heating
- customthe reaction for 8 hours
- customto obtain
- customThis mixture was partitioned by high performance liquid chromatography
出典と根拠
- ORDレコード
- ord-ca0613a1e0fc4d14b7ede5c9f6165983
- 出典データセット
- uspto-grants-2003_12
- 特許番号
- US06660450B2
反応ノート
読み込み中…