Hydrochloric Acid → Benzene, 1-chloro-4-(1,1-dimethylethyl)-
反応式
Cl.[C:2](Cl)([CH3:5])([CH3:4])[CH3:3].[Cl:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>>[C:2]([C:11]1[CH:12]=[CH:13][C:8]([Cl:7])=[CH:9][CH:10]=1)([CH3:5])([CH3:4])[CH3:3]参加物
4
反応条件
- 温度
- 30 °C
実験手順
To 16.9 g of chlorobenzene was added 1.5 g of ferric chloride, and hydrogen chloride gas was blown into the mixture for minutes. Then, 46 g of tert-butyl chloride was added dropwise to the mixture at 30° C. over a period of 1 hour. The mixture was maintained at 30° C. for 2 hours. The reaction mixture was washed with an aqueous solution of sodium carbonate and then with water, and evaporated under reduced pressure to give 25 g of 4-tertbutylchlorobenzene (bp.: 113° C./28 mmHg).
後処理
- waitwas blown into the mixture for minutes
- washThe reaction mixture was washed with an aqueous solution of sodium carbonate
- customwith water, and evaporated under reduced pressure
出典と根拠
- ORDレコード
- ord-544dd4e94c5a45d2b5f5ee6c13c4d0f0
- 出典データセット
- uspto-grants-1983_08
- 特許番号
- US04397864
反応ノート
読み込み中…