Cyclohexanol → Cyclohexyl vinylcarbamate

HRID 434759

反応式

HRID 434759 の反応式
[CH:1]([N:3]=[C:4]=[O:5])=[CH2:2].[CH:6]1([OH:12])[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1>C(OCC)(=O)C>[CH:1]([NH:3][C:4](=[O:5])[O:12][CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1)=[CH2:2]

参加物

4

反応物 2

HCID 7966CyclohexanolHCID 77094Vinyl isocyanate

生成物 1

HCID 85174Cyclohexyl vinylcarbamate

試薬・触媒・溶媒 1

HCID 8857Ethyl Acetate溶媒2 回

反応条件

温度
40 °C

実験手順

69 parts of vinyl isocyanate and 89.5 parts of ethyl acetate are introduced into a reaction vessel and heated to 40° C. A mixture of 110 parts of cyclohexanol and 89.5 parts of ethyl acetate (containing 0.02% of dibutyl-tin dilaurate as catalyst) is added in the course of 1 hour. The mixture is then allowed to react for 2 hours at 40° C. A pale yellow solution is obtained, from which the reaction product crystallizes out on cooling. Blocked isocyanate content: 11.7%.

後処理

  1. additionis added in the course of 1 hour
  2. customto react for 2 hours at 40° C
  3. customA pale yellow solution is obtained, from which the reaction product
  4. customcrystallizes out
  5. temperatureon cooling

出典と根拠

ORDレコード
ord-5b55205706ce450786aa047c315d6db0
出典データセット
uspto-grants-1983_08
特許番号
US04399256

関連ノート

読み込み中…