化工社化工社 化学情報印刷レポート · 研究参考用
Ammonia → N-trimethylsilyl-4-nitrobenzamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | 4-Nitrobenzamide | HCID 12091 | — |
| 反応物 | Hexamethyldisilazane | HCID 13838 | — |
| 反応物 | Naphthalimide | HCID 66491 | — |
| 溶媒 | Butyl Acetate | HCID 31272 | — |
| 生成物 | N-trimethylsilyl-4-nitrobenzamide | HCID 12726300 | — |
反応手順
4.5 ml of hexamethyldisilazane (22 mmoles) were added to a refluxing mixture of 5.0 g (30.1 mmoles) of 4-nitrobenzamide, 100 mg (0.5 mmole) of 1.8-naphthalimide and 20 ml of butyl acetate and the calculated amount of ammonia was evolved after refluxing for 35 minutes. The same experiment without catalyst was carried out and only 16% of the theoretical amount of ammonia was evolved after refluxing for 15 minutes. After refluxing for 1 hour, 83% of that amount of evolved.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04400509 |
| 出典データセット | uspto-grants-1983_08 |
| ORD ID | ord-f9c9ab949fa740f8b6236a8a66d7f676 |
| 出典メモ | uspto-grants-1983_08 |