化工社化工社 化学情報印刷レポート · 研究参考用
O-Cresol → 2,6-Dimethylphenol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | O-Cresol | HCID 335 | — |
| 反応物 | Methanol | HCID 887 | — |
| 反応物 | Calciumoxide | HCID 6850728 | — |
| 触媒 | Titanium oxide (Ti3O) | HCID 162651 | — |
| 触媒 | Ferrous oxide | HCID 449809 | — |
| 触媒 | HCID 178419084 | HCID 178419084 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 2,6-Dimethylphenol | HCID 11335 | — |
反応手順
o-Cresol, methanol and water in a ratio of 1:2.5:2.5 were reacted in the same way as described in Example 1. The catalyst contained iron oxide, vanadium oxide, titanium oxide and calcium oxide in a molar ratio of 100:22:2:1.5. After working up, 2.6-xylenol was obtained with a selectivity of 98%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04400557 |
| 出典データセット | uspto-grants-1983_08 |
| ORD ID | ord-0d0ea9ca75c5445d91490438f7cd5b5d |
| 出典メモ | uspto-grants-1983_08 |