化工社化工社 化学情報印刷レポート · 研究参考用
Morpholine → N-(1-adamantyl)morpholine-4-carbothioamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Morpholine | HCID 8083 | — |
| 反応物 | Adamantyl isothiocyanate | HCID 107279 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | N-(1-adamantyl)morpholine-4-carbothioamide | HCID 2828003 | — |
反応手順
The thiourea is prepared by reacting 5.0 g. (0.026 mole) of 1-adamantyl isothiocyanate with 2.5 g. (0.029 mole) of morpholine in 250 ml. of ether for ca. 1 hr. at room temperature. The solid which separates is collected and combined with additional compound from concentration of ether filtrate to a small volume: 6.65 g. (91 percent), m.p. 145-147. The analytical sample is recrystallized from ether, m.p. 148.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04007181 |
| 出典データセット | uspto-grants-1977_02 |
| ORD ID | ord-6912602631aa45beb0219a09ad070591 |
| 出典メモ | uspto-grants-1977_02 |