化工社化工社 化学情報印刷レポート · 研究参考用
Methyl Benzoin → Cinnamyl methacrylate 1-naphthyl methacrylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl Benzoin | HCID 98097 | — |
| 反応物 | Cinnamyl methacrylate | HCID 228230 | — |
| 反応物 | Naphthyl methacrylate | HCID 4064248 | — |
| 反応物 | Nitrosocyclohexane | HCID 11768540 | — |
| 反応物 | p-Xylylene diacrylate | HCID 11961420 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 溶媒 | 1-Chloronaphthalene | HCID 7003 | — |
| 溶媒 | O-Xylene | HCID 7237 | — |
| 生成物 | Cinnamyl methacrylate 1-naphthyl methacrylate | HCID 86734496 | — |
反応手順
A mixture of 2.00 g poly(cinnamyl methacrylate/-1-naphthyl methacrylate), 1.50 g 1-naphthyl methacrylate, 0.25 g p-xylylene diacrylate, 0.40 g benzoin methyl ether, 0.05 g 20% nitrosocyclohexane dimer in 1-chloronaphthalene, and 3.00 g xylene was prepared. Poly(cinnamyl methacrylate/1-naphthyl methacrylate) was prepared by thermally copolymerizing equal parts of cinnamyl methacrylate and 1-naphthyl methacrylate in a benzene solution using an azonitrile initiator. The polymer was precipitated from solution and washed prior to use.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04008083 |
| 出典データセット | uspto-grants-1977_02 |
| ORD ID | ord-9a576419313945b99d3a9a36026ccab0 |
| 出典メモ | uspto-grants-1977_02 |