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Cadmium acetate, dihydrate → Cadmium Bis (2-trichloromethyl-3-oxazolidinecarbodithioate)
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Cadmium acetate, dihydrate | HCID 6537495 | — |
| 反応物 | Triethylammonium 2-Trichloromethyl-3-oxazolidinecarbodithioate | HCID 22766662 | — |
| 触媒 | Copper | HCID 23978 | — |
| 触媒 | Zinc | HCID 23994 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | Cadmium Bis (2-trichloromethyl-3-oxazolidinecarbodithioate) | HCID 86733118 | — |
反応手順
Cadmium acetate dihydrate (6.7g., 0.025 mole) was stirred into a solution of 18.4g. (0.050 mole) of triethylammonium 2-trichloromethyloxazolidine-3-carbodithioate in 300 ml. of 95% ethanol at 30° C. The precipitate was filtered off at 5° C. and water-washed on the filter. After drying in a vacuum desiccator, there was obtained 12.8 g. of white crystals, melting at 223°-225° C. with decomposition. Its infra-red spectrum confirmed the desired structure and was essentially the same as that of the corresponding zinc and copper salts.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04008244 |
| 出典データセット | uspto-grants-1977_02 |
| ORD ID | ord-ec71b39ac5694a6ea8696c061c5eb757 |
| 出典メモ | uspto-grants-1977_02 |