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Hexachlorocyclopentadiene → 6-Tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hexachlorocyclopentadiene | HCID 6478 | — |
| 反応物 | tert-Butyl-1,4-benzoquinone | HCID 19211 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 6-Tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione | HCID 20300626 | — |
反応手順
Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained, melting at 124° -125° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04009200 |
| 出典データセット | uspto-grants-1977_02 |
| ORD ID | ord-bebd30c4a31c439c8ca2e9df4fd11cbf |
| 出典メモ | uspto-grants-1977_02 |