Potassium Hydroxide → N,N'-Heptamethylenebis(4-n-butoxybenzamide)

HRID 436635

反応式

HRID 436635 の反応式
[CH2:1]([O:5][C:6]1[CH:14]=[CH:13][C:9]([C:10](Cl)=[O:11])=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[CH2:15]([NH2:23])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][NH2:22].[OH-:24].[K+]>C(Cl)CCl>[CH2:1]([O:5][C:6]1[CH:14]=[CH:13][C:9]([C:10]([NH:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][NH:23][C:10](=[O:11])[C:9]2[CH:13]=[CH:14][C:6]([O:24][CH2:1][CH2:2][CH2:3][CH3:4])=[CH:7][CH:8]=2)=[O:11])=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4]

参加物

5

反応物 3

HCID 14797Potassium HydroxideHCID 695331,7-HeptanediamineHCID 1185614-Butoxybenzoyl chloride

生成物 1

HCID 21452867N,N'-Heptamethylenebis(4-n-butoxybenzamide)

試薬・触媒・溶媒 1

HCID 111,2-Dichloroethane溶媒

実験手順

m.p. 151°-152° C., 20.0 g., was prepared as in Example 1 using 4-n-butoxybenzoyl chloride (prepared from 27.2 g. of 4-n-butoxybenzoic acid as in Example 6) in 200 ml. of ethylene dichloride, 6.5 g. of 1,7-heptanediamine, 200 ml. of 10% aqueous potassium hydroxide solution, 500 ml. of ethylene dichloride and recrystallization from ethanol using decolorizing charcoal.

後処理

  1. customof ethylene dichloride and recrystallization from ethanol using

出典と根拠

ORDレコード
ord-4ba03344623a4bcc907cc4528b18bc26
出典データセット
uspto-grants-1977_02
特許番号
US04009208

関連ノート

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