Potassium Hydroxide → N,N'-Heptamethylenebis(4-pentyloxybenzamide)

HRID 436636

反応式

HRID 436636 の反応式
[CH2:1]([O:6][C:7]1[CH:15]=[CH:14][C:10]([C:11](Cl)=[O:12])=[CH:9][CH:8]=1)[CH2:2][CH2:3][CH2:4][CH3:5].[CH2:16]([NH2:24])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][NH2:23].[OH-:25].[K+]>C(Cl)CCl>[CH2:1]([O:6][C:7]1[CH:15]=[CH:14][C:10]([C:11]([NH:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][NH:24][C:11](=[O:12])[C:10]2[CH:14]=[CH:15][C:7]([O:25][CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])=[CH:8][CH:9]=2)=[O:12])=[CH:9][CH:8]=1)[CH2:2][CH2:3][CH2:4][CH3:5]

参加物

5

反応物 3

HCID 14797Potassium HydroxideHCID 695331,7-HeptanediamineHCID 94910p-Pentoxybenzoyl chloride

生成物 1

HCID 21453005N,N'-Heptamethylenebis(4-pentyloxybenzamide)

試薬・触媒・溶媒 1

HCID 111,2-Dichloroethane溶媒

実験手順

m.p. 155°-156° C., 29.9 g., was prepared as in Example 1 using 50 g. of 4-pentyloxybenzoyl chloride in 200 ml. of ethylene dichloride, 13.0 g. of 1,7-heptanediamine, 250 ml. of 10% aqueous potassium hydroxide solution, 500 ml. of ethylene dichloride and recrystallization from ethanol.

後処理

  1. custom, was prepared as in Example 1 using 50 g
  2. customof ethylene dichloride and recrystallization from ethanol

出典と根拠

ORDレコード
ord-237b5978bc3f4f54b0c9a58e51765442
出典データセット
uspto-grants-1977_02
特許番号
US04009208

関連ノート

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