Potassium Hydroxide → HCID 21452860、化合物

HRID 436655

反応式

HRID 436655 の反応式
[F:1][C:2]([F:14])([F:13])[O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8](Cl)=[O:9])=[CH:6][CH:5]=1.[CH2:15]([NH2:28])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][NH2:27].[OH-:29].[K+]>C(Cl)CCl>[F:1][C:2]([F:14])([F:13])[O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8]([NH:28][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][NH:27][C:8](=[O:9])[C:7]2[CH:11]=[CH:12][C:4]([O:29][C:2]([F:1])([F:13])[F:14])=[CH:5][CH:6]=2)=[O:9])=[CH:6][CH:5]=1

参加物

5

反応物 3

HCID 14797Potassium HydroxideHCID 177271,12-DodecanediamineHCID 1421104-(Trifluoromethoxy)benzoyl Chloride

生成物 1

HCID 21452860HCID 21452860、化合物

試薬・触媒・溶媒 1

HCID 111,2-Dichloroethane溶媒

実験手順

m.p. 158°-159° C., 11.3 g., was prepared as in Example 1 using 24.8 g. of 4-trifluoromethoxybenzoyl chloride in 150 ml. of ethylene dichloride, 10.0 g. of 1,12-dodecanediamine, 60 ml. of 10% aqueous potassium hydroxide solution, 350 ml. of ethylene dichloride and recrystallization twice from ethanol and once from isopropyl alcohol.

後処理

  1. custom, was prepared as in Example 1 using 24.8 g
  2. customof ethylene dichloride and recrystallization twice from ethanol

出典と根拠

ORDレコード
ord-dcc3d143b4c94612acec4c4e25b57104
出典データセット
uspto-grants-1977_02
特許番号
US04009208

関連ノート

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