Diiodomethane → 2-Cyclopropylnaphthalene

HRID 436674

反応式

HRID 436674 の反応式
[CH:1]([C:3]1[CH:12]=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1)=[CH2:2].I[CH2:14]I>[Cu].[Zn].C(OCC)C>[CH:1]1([C:3]2[CH:12]=[CH:11][C:10]3[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=3)[CH:4]=2)[CH2:14][CH2:2]1

参加物

5

反応物 2

HCID 6346DiiodomethaneHCID 132302-Vinylnaphthalene

生成物 1

HCID 146686962-Cyclopropylnaphthalene

試薬・触媒・溶媒 2

HCID 10290809Zinc copper couple触媒HCID 3283Diethyl Ether溶媒

実験手順

A mixture of 15.5 g. of 2-vinylnaphthalene, 23 g. of diiodomethane, 19.6 g. of zinc-copper couple (comprising 19.5 g. of zinc and 0.1 g. of copper) and 500 ml. of diethyl ether is refluxed for eight hours; the cooled mixture is then filtered, washed with dilute hydrochloric acid, washed with water to neutrality, dried and evaporated to yield 2-cyclopropylnaphthalene.

後処理

  1. additionA mixture of 15.5 g
  2. filtrationthe cooled mixture is then filtered
  3. washwashed with dilute hydrochloric acid
  4. washwashed with water to neutrality
  5. customdried
  6. customevaporated

出典と根拠

ORDレコード
ord-3501764fa95648adb212bdc65f203d58
出典データセット
uspto-grants-1977_02
特許番号
US04009197

関連ノート

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