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llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.8.0
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Carbon Dioxide → Isophorone diamine

HRID 436724
ノート
印刷プレビュー

反応式

HRID 436724 の反応式
[N:1]([CH:4]1[CH2:9][C:8]([CH3:14])([CH2:10][N:11]=C=O)[CH2:7][C:6]([CH3:16])([CH3:15])[CH2:5]1)=C=O.CP1(=O)CCC=C1.CP1(=O)CC=CC1.C(=O)=O.C(O)(=O)C(C)=C>CN(C)C=O>[NH2:1][CH:4]1[CH2:9][C:8]([CH3:14])([CH2:10][NH2:11])[CH2:7][C:6]([CH3:16])([CH3:15])[CH2:5]1
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

7

反応物 5

HCID 280Carbon DioxideHCID 4093Methacrylic AcidHCID 701042,3-Dihydro-1-methyl-1H-phosphole 1-oxideHCID 702562,5-Dihydro-1-methyl-1H-phosphole 1-oxideHCID 169132Isophorone diisocyanate

生成物 1

HCID 17857Isophorone diamine収率 140%

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒3 回

反応条件

温度
50 °C

実験手順

After the prepolymer has been cooled to 50° C., 695 parts by weight of dimethyl formamide and 44.4 parts by weight (0.2 mol) of 1-isocyanato-3,3,5-trimethyl-5-isocyanato methyl cyclohexane are added. 34.8 parts by weight (0.2 mol) of a mixture of 2,4- and 2,6-tolylene diisocyanate in a ratio of 8:2, and 2.4 parts by weight (0.02 mol) of a mixture of 1-methyl-1-phospha -2-cyclopenten-1-oxide and 1-methyl-1-phospha -3-cyclopenten-1-oxide, are added to the resulting solution. When the evolution of carbon dioxide has virtually stopped, 17.2 parts by weight (0.2 mol) of methacrylic acid in 17.2 parts by weight of dimethyl formamide are added, followed by stirring at 80° C. until a clear solution is formed. Chain extension with 48 parts by weight (0.28 mol) of 1-amino-3,3,5-trimethyl-5-aminomethyl cyclohexane in 100 parts by weight of dimethyl formamide at 25° C. gives a solution of a polyurethane acyl urea having a viscosity of 1650 cP at 24° C.

後処理

  1. customis formed

出典と根拠

ORDレコード
ord-d58d548c6fd241158bf5c45fa0106329
出典データセット
uspto-grants-1977_06
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04028310

反応ノート

読み込み中…

このページの内容参加物反応条件実験手順後処理出典と根拠反応ノート