化工社化工社 化学情報印刷レポート · 研究参考用
Formaldehyde → 3-Methyl-2-buten-1-OL
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Formaldehyde | HCID 712 | — |
| 反応物 | Isobutane | HCID 6360 | — |
| 反応物 | Butane | HCID 7843 | — |
| 反応物 | 1-Butene | HCID 7844 | — |
| 反応物 | 1,3-Butadiene | HCID 7845 | — |
| 反応物 | Isobutylene | HCID 8255 | — |
| 反応物 | trans-2-BUTENE | HCID 62695 | — |
| 反応物 | cis-2-BUTENE | HCID 5287573 | — |
| 生成物 | 3-Methyl-2-buten-1-OL | HCID 11173 | — |
| 生成物 | 3-Methyl-3-buten-1-ol | HCID 12988 | — |
反応手順
The procedure of Example 1 was repeated except for using 150 ml of spent BB (composition: isobutene 47.3%, isobutane 2.2%, n-butane 8.9%, butene-1 27.6%, trans-2-butene 8.8%, cis-2-butene 4.4% and butadiene 0.87%) as a isobutene source in place of isobutene. Conversion of paraformaldehyde was 97.0 mole%. There were obtained 62.0 mole% of 3-methyl-3-butene-1-ol and 7.1 mole% of 3-methyl-2-butene-1-ol based on the paraformaldehyde reacted.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04028424 |
| 出典データセット | uspto-grants-1977_06 |
| ORD ID | ord-234a96b099dc442d87cf6be6d7a40e74 |
| 出典メモ | uspto-grants-1977_06 |