化工社化工社 化学情報印刷レポート · 研究参考用
Water → BIS-(beta-M-CHLOROBENZAMIDOETHYL)SULFIDE
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Benzoyl chloride, 3-chloro- | HCID 69252 | — |
| 反応物 | 2,2'-Thiobis(ethanamine) | HCID 70096 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | BIS-(beta-M-CHLOROBENZAMIDOETHYL)SULFIDE | HCID 22749424 | — |
反応手順
To a solution of bis-(β-aminoethyl)sulfide (2.5 g., 0.021 M) and sodium hydroxide (1.6 g., 0.04 M) in 20 ml. of water and 40 ml. of ether was added a solution of m-chlorobenzoyl chloride (7.0 g., 0.04 M) in 15 ml. of ether at 10°-20° C. A precipitate appeared. The mixture was stirred 45 minutes at room temperature and the solid filtered, washed with water and dried. The product was a white solid. m.p. 150°-152° C. Its structure was confirmed by IR spectroscopy. Yield: 7.0 g. (88%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04030911 |
| 出典データセット | uspto-grants-1977_06 |
| ORD ID | ord-2f9b99d128c0462e9224845c3547914c |
| 出典メモ | uspto-grants-1977_06 |