4-Nonylphenol → Strontium nonylphenolate carbonate

HRID 440376

反応式

HRID 440376 の反応式
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]1[CH:11]=[CH:12][C:13]([OH:16])=[CH:14][CH:15]=1.[OH-:17].[Sr+2:18].[OH-:19]>O>[CH2:9]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][C:15]=1[O-:17])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1].[Sr+2:18].[CH2:9]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][C:15]=1[O-:17])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1].[C:13](=[O:16])([O-:19])[O-:17]

参加物

4

反応物 2

HCID 17524-NonylphenolHCID 87672Strontium hydroxide

生成物 1

HCID 86749491Strontium nonylphenolate carbonate収率 15%

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
155 °C

実験手順

To a mixture of 134 g of nonylphenol, 174 g of process oil (Mentor 28:Esso Petroleum) and 62 g of an aromatic hydrocarbon solvent (Solvesso 100: Esso Petroleum) was added 243 g of strontium hydroxide (octahydrate salt) gradually to disperse it, the mixture was subjected to reaction at 105° C. for one hour, and water was completely removed at 130° C. Carbon dioxide (10 L/hour) was blown thereinto for 5 hours to progress reaction, and the mixture was gradually heated to 155° C. to continue reaction while water was distilled off, and then filtered to give a brown solution of an overbased strontium nonylphenolate-carbonate complex (Sr=15%; metal ratio=2.9) (this product is designated S-5).

後処理

  1. additionto disperse it
  2. customthe mixture was subjected to reaction at 105° C. for one hour
  3. customwater was completely removed at 130° C
  4. customreaction
  5. distillationwas distilled off
  6. filtrationfiltered

出典と根拠

ORDレコード
ord-2f95ff274fec4428ae35d277a196a878
出典データセット
uspto-grants-1996_05
特許番号
US05519076

関連ノート

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