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5-[(4-Chlorophenyl)methylidene]-2,2-dimethylcyclopentan-1-one → 5-(4-Chlorobenzyl)-2,2-dimethylcyclopentanone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 5-[(4-Chlorophenyl)methylidene]-2,2-dimethylcyclopentan-1-one | HCID 53421021 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 触媒 | HCID 178418390 | HCID 178418390 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 5-(4-Chlorobenzyl)-2,2-dimethylcyclopentanone | HCID 11424896 | — |
反応手順
5 g of 2-(4-chlorobenzylidene)-5,5-dimethylcylopentanone (prepared in Example 5) was dissolved in 40 ml of ethanol, and 60 mg palladium-carbon (10%) was added to the mixture. The hydrogenation reaction was carried out under normal pressure until theoretical amount of hydrogen was absorbed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05519160 |
| 出典データセット | uspto-grants-1996_05 |
| ORD ID | ord-374bf906581b40649dcba35c765543d2 |
| 出典メモ | uspto-grants-1996_05 |