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5-(1-Naphthyl)-4-pentyn-1-ol → 5-(Naphth-1-yl)pentanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 5-(1-Naphthyl)-4-pentyn-1-ol | HCID 19955557 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 5-(Naphth-1-yl)pentanol | HCID 10353200 | 93.3% |
反応手順
A mixture of 3.5 grams (0.017 mole) of 5-(naphth-1-yl)-4-pentyn-1-ol and 0.5 gram (catalyst) of 10% palladium on carbon in 30 mL of ethanol was shaken in a Parr hydrogenator until the theoretical amount of hydrogen gas was taken up. The reaction mixture was filtered to remove the catalyst, and the filtrate was concentrated under reduced pressure, yielding 3.4 grams of 5-(naphth-1-yl)pentanol. The NMR spectrum was consistent with the proposed structure.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05521192 |
| 出典データセット | uspto-grants-1996_05 |
| ORD ID | ord-ccbb9eb492614f1abada5b33b9b272a6 |
| 出典メモ | uspto-grants-1996_05 |