化工社化工社 化学情報印刷レポート · 研究参考用
Undecanoic Acid → Undecanoyl chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Undecanoic Acid | HCID 8180 | — |
| 反応物 | Oxalyl chloride | HCID 65578 | — |
| 触媒 | Dimethylformamide | HCID 6228 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Undecanoyl chloride | HCID 87287 | 39.8% |
反応手順
Under a nitrogen atmosphere, a solution of 5.0 grams (0.027 mole) of undecanoic acid in 75 mL of methylene chloride was stirred and 2.8 ml (0.032 mole) of oxalyl chloride and 5 drops of N,N-dimethylformamide were added. Upon completion of addition, the reaction mixture was stirred for about 16 hours, then it was concentrated under reduced pressure, yielding 2.2 grams of undecanoyl chloride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05521192 |
| 出典データセット | uspto-grants-1996_05 |
| ORD ID | ord-6e366cb4a7924555947d4f40ba8a8ff0 |
| 出典メモ | uspto-grants-1996_05 |