Ammonia → HCID 135623125、化合物
反応式
[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8](=O)[CH2:9][S:10]([CH3:12])=[O:11].[NH3:14]>>[NH:14]=[C:8]([C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=1[OH:1])[CH2:9][S:10]([CH3:12])=[O:11]参加物
3
実験手順
A solution of 2'-hydroxy-2-(methylsulfinyl)acetophenone (23.5 g, 0.12 mole) in liquid ammonia (450 ml) was stirred at -33° for 9 hrs. The ammonia was allowed to evaporate. The residue was recrystallized from methanol to give yellow crystals (18.5 g, 79%), mp 194°-195°.
後処理
- customto evaporate
- customThe residue was recrystallized from methanol
出典と根拠
- ORDレコード
- ord-ceb18f29f8764ff5ac5be5c783fceb03
- 出典データセット
- uspto-grants-1977_08
- 特許番号
- US04039579
反応ノート
読み込み中…