2-Nitro-2'-hydroxy-3',5'-bis(tert-amyl)azobenzene → 2-(2-hydroxy-3-(alpha-methylbenzyl)-5-methylphenyl)-2H-benzotriazole

HRID 441515

反応式

HRID 441515 の反応式
OC1C(C(CC)(C)C)=CC(C(CC)(C)C)=CC=1N=NC1C=CC=CC=1[N+]([O-])=O.[OH:29][C:30]1[C:35]([CH:36]([CH3:43])[C:37]2[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=2)=[CH:34][C:33]([CH3:44])=[CH:32][C:31]=1[N:45]=[N:46][C:47]1[CH:52]=[CH:51][CH:50]=[CH:49][C:48]=1[N+:53]([O-])=O>>[OH:29][C:30]1[C:35]([CH:36]([CH3:43])[C:37]2[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=2)=[CH:34][C:33]([CH3:44])=[CH:32][C:31]=1[N:45]1[N:53]=[C:48]2[CH:49]=[CH:50][CH:51]=[CH:52][C:47]2=[N:46]1

参加物

3

反応物 2

HCID 1041112-Nitro-2'-hydroxy-3',5'-bis(tert-amyl)azobenzeneHCID 1355888052'-Hydroxy-3'-(alpha-methylbenzyl)-5'-methyl-2-nitroazobenzene

生成物 1

HCID 198647052-(2-hydroxy-3-(alpha-methylbenzyl)-5-methylphenyl)-2H-benzotriazole

実験手順

When in Example 1, the 2'hydroxy-3',5'-di-tert-amyl-2-nitroazobenzene is replaced by an equivalent amount of 2'-hydroxy-3'-(α-methylbenzyl)-5'-methyl-2-nitroazobenzene, the product 2-(2-hydroxy-3-(α-methylbenzyl)-5-methylphenyl)-2H-benzotriazole is obtained.

出典と根拠

ORDレコード
ord-a6583f8db3d044deb9f9bf68c3e923b3
出典データセット
uspto-grants-1977_08
特許番号
US04041044

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