Hydrochloric Acid → (6-Chloro-2-oxohexyl) triphenylphosphonium chloride

HRID 441603ノート

反応式

HRID 441603 の反応式
[Cl-:1].[O:2]1[CH2:7][CH2:6][CH2:5][CH2:4][C:3]1=[CH:8][P+:9]([C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.Cl>>[Cl-:1].[Cl:1][CH2:7][CH2:6][CH2:5][CH2:4][C:3](=[O:2])[CH2:8][P+:9]([C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

参加物

3

反応物 2

HCID 313Hydrochloric AcidHCID 73680070[(tetrahydro-2H-pyran-2-ylidene)methyl]triphenylphosphonium chloride

生成物 1

HCID 20526427(6-Chloro-2-oxohexyl) triphenylphosphonium chloride

実験手順

A solution consisting of 18.5 parts of [(tetrahydro-2H-pyran-2-ylidene)methyl]triphenylphosphonium chloride in 100 parts by volume of concentrated hydrochloric acid is heated at the reflux temperature for about 36 hours, then is cooled to room temperature. The solvent is removed by distillation under reduced pressure to afford (6-chloro-2-oxohexyl)triphenyl-phosphonium chloride, identical with the product of Example 2.

後処理

  1. temperatureis heated at the reflux temperature for about 36 hours
  2. customThe solvent is removed by distillation under reduced pressure

出典と根拠

ORDレコード
ord-031a4fa3dbd347f598fe8324b6ccb3c9
出典データセット
uspto-grants-1977_08
特許番号
US04041050

反応ノート

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