Hydrazine → (4,5,6,7-Tetrahydro-1H-[1,3]diazepin-2-yl)-hydrazine
反応式
Cl.[NH:2]1[CH2:8][CH2:7][CH2:6][CH2:5][N:4]=[C:3]1[NH:9][NH2:10].CSC1NCCCCN=1.NN>C(O)C>[NH:4]1[CH2:5][CH2:6][CH2:7][CH2:8][N:2]=[C:3]1[NH:9][NH2:10]参加物
5
実験手順
The starting material, 4,5,6,7-tetrahydro-1H-1,3-diazepin-2-ylhydrazine hydrochloride, is prepared as follows: 4,5,6,7-tetrahydro-2-methylthio-1H-1,3-diazepine (McKay and Kreling. Can. J. Chem. 35 1438 (1957) and hydrazine are added to ethanol, and the solution then heated to yield 4,5,6,7-tetrahydro-1H-1,3-diazepin-2-ylhydrazine hydroidide, melting point 133° -135° C. If the latter compound is treated with silver chloride in aqueous or ethanol solution, the hydrochloride salt is obtained, melting point 192°-193° C.
後処理
- temperaturethe solution then heated
出典と根拠
- ORDレコード
- ord-ca7abe6b9f384d0eb92a826f211fd7db
- 出典データセット
- uspto-grants-1977_08
- 特許番号
- USRE029358
反応ノート
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