Acetylacetone → 2,8-Dimethyldibenzofuran

HRID 441760

反応式

HRID 441760 の反応式
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][C:9]2[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][CH:10]=2)=[CH:4][CH:3]=1.C(CC(=O)C)(=O)C>C([O-])(=O)C.[Pd+2].C([O-])(=O)C>[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[O:8][C:9]3[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][C:10]=3[C:6]=2[CH:7]=1

参加物

4

反応物 2

HCID 31261AcetylacetoneHCID 74098Benzene, 1,1'-oxybis[4-methyl-

生成物 1

HCID 6393192,8-Dimethyldibenzofuran収率 20.6%

試薬・触媒・溶媒 1

HCID 167845palladium(II) acetate触媒

実験手順

This example was carried out under the same reaction conditions as in Example 1 except that 29.0 g of 4,4'-dimethyldiphenyl ether, 0.067 g (0.30 m. mole) of palladium acetate, and 0.030 g of acetylacetone (0.30 m. mole) were employed and the mixture was reacted for 7 hours. As a result, 5.9 g (30 m. moles) of 2,8 -dimethyldibenzofuran was obtained and 1.9 g (4.7 m. moles) of the dimer also obtained.

後処理

  1. customthe mixture was reacted for 7 hours

出典と根拠

ORDレコード
ord-1c4aa2f80db2461c8e90f3be876f0c41
出典データセット
uspto-grants-1977_08
特許番号
US04042603

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