Oxygen → Formamide, N,N-dioctyl-

反応式

[CH3:1][N:2]([CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[O:19]=O>>[CH2:11]([N:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:1]=[O:19])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

参加物

反応物 2

HCID 977Oxygen

HCID 78202N-Methyl-N-octyl-1-octanamine2 回

生成物 1

HCID 221420Formamide, N,N-dioctyl-収率 4.5%

実験手順

By essentially the procedure of Example 1, a tube was charged with 40 g of methyldioctylamine and 1.0 g of CuCl2. 2H2O. The reaction was run at 109°-120° C. for 25 min while oxygen (0.2 mole) was injected incrementally at 160-275 psi. GC/MS analysis showed a 72.0% conversion of methyldioctylamine and a 4.5% yield of dioctylformamide.

出典と根拠

ORDレコード: ord-77361349d68144e39a3db9d888a8dfa9
出典データセット: uspto-grants-1977_08
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04042621

反応ノート

読み込み中…