化工社化工社 化学情報印刷レポート · 研究参考用
Phenyl 2-chloro-2-oxoacetate → Carbonochloridic acid, 4-methoxyphenyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Phenyl 2-chloro-2-oxoacetate | HCID 11423990 | — |
| 反応物 | 4-Methoxyphenyl chloroglyoxylate | HCID 53706464 | — |
| 触媒 | Tetraphenylphosphonium Chloride | HCID 164911 | — |
| 生成物 | Carbonochloridic acid, 4-methoxyphenyl ester | HCID 82128 | — |
反応手順
The decarbonylation reaction was repeated in the manner as described in Example 70, except that the amount of tetraphenylphosphonium chloride was changed as set forth in Table 11, that the phenyl chloroglyoxylate was replaced with 1.396 mmol. of 4-methoxyphenyl chloroglyoxylate (4-MeO--PCG), and that the reaction temperature and reaction period were changed as set forth in Table 11. The results are also set forth in Table 11.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05892091 |
| 出典データセット | uspto-grants-1999_04 |
| ORD ID | ord-d83da159e16c4b9983a417cd4ed1f36c |
| 出典メモ | uspto-grants-1999_04 |