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HRID 443082作成日:2026年10月26日

Phenyl 2-chloro-2-oxoacetate → Carbonochloridic acid, 4-methoxyphenyl ester

https://huagongshe.com/reaction/443082

反応式

関与物質

役割名称HCID仕込み量
反応物Phenyl 2-chloro-2-oxoacetateHCID 11423990—
反応物4-Methoxyphenyl chloroglyoxylateHCID 53706464—
触媒Tetraphenylphosphonium ChlorideHCID 164911—
生成物Carbonochloridic acid, 4-methoxyphenyl esterHCID 82128—

反応手順

The decarbonylation reaction was repeated in the manner as described in Example 70, except that the amount of tetraphenylphosphonium chloride was changed as set forth in Table 11, that the phenyl chloroglyoxylate was replaced with 1.396 mmol. of 4-methoxyphenyl chloroglyoxylate (4-MeO--PCG), and that the reaction temperature and reaction period were changed as set forth in Table 11. The results are also set forth in Table 11.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US05892091
出典データセットuspto-grants-1999_04
ORD IDord-d83da159e16c4b9983a417cd4ed1f36c
出典メモuspto-grants-1999_04