化工社化工社 化学情報印刷レポート · 研究参考用
Ethyl Acetate → (2E,6E)-2-[(3E)-4,8-Dimethylnona-3,7-dien-1-YL]-6-methylocta-2,6-diene-1,8-diol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethyl Acetate | HCID 8857 | — |
| 反応物 | Aluminiumhydride | HCID 21584524 | — |
| 反応物 | HCID 53654873 | HCID 53654873 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | (2E,6E)-2-[(3E)-4,8-Dimethylnona-3,7-dien-1-YL]-6-methylocta-2,6-diene-1,8-diol | HCID 6373042 | — |
反応手順
The ester thus obtained was further reduced by aluminum hydride (prepared from 760 mg of lithium aluminum hydride and 880 mg of aluminum chloride) in 7 ml of ether. After completion of the reaction, ethyl acetate was added to the reaction mixture, and the precipitate was filtered off. The filtrate was evaporated to dryness, yielding 3.5 g of the desired product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04260551 |
| 出典データセット | uspto-grants-1981_04 |
| ORD ID | ord-6417daee1ff942c6842215cc7af87313 |
| 出典メモ | uspto-grants-1981_04 |