Allylamine → N-allyl-4-nitro-2-trichloromethylphenylsulfenamide
反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10]Cl)=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2].[CH2:16]([NH2:19])[CH:17]=[CH2:18]>>[CH2:16]([NH:19][S:10][C:7]1[CH:8]=[CH:9][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][C:6]=1[C:12]([Cl:15])([Cl:14])[Cl:13])[CH:17]=[CH2:18]参加物
3
実験手順
As in Example 4, 61.4 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride is reacted with 23 g of allylamine. The hydrochloride is filtered off and the ether phase is concentrated. There is obtained 62 g (95% of theory) of N-allyl-4-nitro-2-trichloromethylphenylsulfenamide as a pale oil.
後処理
- filtrationThe hydrochloride is filtered off
- concentrationthe ether phase is concentrated
出典と根拠
- ORDレコード
- ord-6e3c06f0d8a24476a4061dc20e4e31d1
- 出典データセット
- uspto-grants-1981_04
- 特許番号
- US04261924
反応ノート
読み込み中…