化工社化工社 化学情報印刷レポート · 研究参考用
Dichloromethane → HCID 57171531、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dichloromethane | HCID 6344 | — |
| 反応物 | Phenylboronic Acid | HCID 66827 | — |
| 反応物 | 4-Chloro-3-ethylphenol | HCID 84223 | — |
| 生成物 | HCID 57171531 | HCID 57171531 | — |
反応手順
3-ethyl-4-chlorophenol (2.0 g, 0.013 mol), phenylboronic acid (4.7 g, 0.038 mol), TEA (11 mL, 0.077 mol), cupric acetate (4.2 g, 0.023 mol) and DCM (60 mL, 0.9 mol) were added to a 100 mL oven dried flask and the reaction was stirred at rt for 24 h. The solvent was then removed under reduced pressure and the resulting residue was purified by flash chromatography (5% EtOAc in Hexane).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08481733B2 |
| 出典データセット | uspto-grants-2013_07 |
| ORD ID | ord-468ee86025da4a8694d036ab3c535b72 |
| 出典メモ | uspto-grants-2013_07 |