Methylhydrazine → HCID 59394553、化合物
反応式
[CH3:1][C:2]1([C:5](=O)[CH2:6][C:7]#[N:8])[CH2:4][CH2:3]1.[CH3:10][NH:11][NH2:12]>CO>[CH3:10][N:11]1[C:7]([NH2:8])=[CH:6][C:5]([C:2]2([CH3:1])[CH2:4][CH2:3]2)=[N:12]1参加物
4
実験手順
A solution of 3-(1-methyl-cyclopropyl)-3-oxo-propionitrile (1.0 g, 8.1 mmol), methylhydrazine (0.56 g, 12.2 mmol) and MeOH (40 mL) is heated at 80° C. for 16 h. The solution is then concentrated in vacuo and the residue is suspended in 5 mL DCM and 20 mL heptane, filtered to give product. MS (ESI) m/z 152.3 (M+1).
後処理
- concentrationThe solution is then concentrated in vacuo
- filtration20 mL heptane, filtered
- customto give product
出典と根拠
- ORDレコード
- ord-c55d150efd304fc9a9139d3ce83d7ee0
- 出典データセット
- uspto-grants-2013_07
- 特許番号
- US08486954B2
反応ノート
読み込み中…