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N-(4-Hydroxybenzoyl)glycine tert-butyl ester → N-[4-(2-Cyclopenta-2-en-1-ylethoxy)benzoyl]glycine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N-(4-Hydroxybenzoyl)glycine tert-butyl ester | HCID 10682169 | — |
| 反応物 | 2-Cyclopentene-1-ethanol | HCID 10964444 | — |
| 生成物 | N-[4-(2-Cyclopenta-2-en-1-ylethoxy)benzoyl]glycine | HCID 66812182 | 72% |
反応手順
The same reaction as in Example 1 (1b) was conducted using N-(4-hydroxybenzoyl)glycine tert-butyl ester (157 mg, 0.625 mmol) prepared in Example 1 (1a) and 2-cyclopenta-2-en-1-ylethanol (which is the compound disclosed in J. Org. Chem., (2000), 65, 4241-4250, 85 mg, 0.75 mmol) to give 128 mg of the title compound (white powder, yield: 72%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08497397B2 |
| 出典データセット | uspto-grants-2013_07 |
| ORD ID | ord-177f8dac70334486b69579511e496689 |
| 出典メモ | uspto-grants-2013_07 |