化工社化工社 化学情報印刷レポート · 研究参考用
Methyl Isocyanate → 2-Thiopheneacetonitrile, α-[[[(methylamino)carbonyl]oxy]imino]-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl Isocyanate | HCID 12228 | — |
| 反応物 | Alpha-Oximino-2-Thienylacetonitrile | HCID 73667355 | — |
| 触媒 | Triethylamine | HCID 8471 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | 2-Thiopheneacetonitrile, α-[[[(methylamino)carbonyl]oxy]imino]- | HCID 54469230 | — |
反応手順
To a solution of 3.04 g. (0.02 mole) of alphaoximino-2-thienylacetonitrile and 2 drops of triethylamine in 50 ml. of ether was added 1.14 g. (0.02 mole) of methylisocyanate in 10 ml. of ether. After 1 hour the solid was filtered and crystallized from benzene to give 3.8 g. of product melting at 154°-155° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04061764 |
| 出典データセット | uspto-grants-1977_12 |
| ORD ID | ord-867d5ad1b26e43df92c8a83a35b5e159 |
| 出典メモ | uspto-grants-1977_12 |