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M-Cresol → m-Cresyl 3-indolylglyoxylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | M-Cresol | HCID 342 | — |
| 反応物 | Pyridine | HCID 1049 | — |
| 反応物 | 3-Indoleglyoxylyl chloride | HCID 89952 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | m-Cresyl 3-indolylglyoxylate | HCID 21393607 | — |
反応手順
3-Indolylglyoxylyl chloride (104 g. ) was stirred in diethyl ether (500 ml.) and treated with m-cresol (108 g.) followed by pyridine (79 g.). After stirring for 30 minutes the solid product was collected by filtration, washed with water then with acetonitrile and dried to give m-cresyl 3-indolylglyoxylate as a yellow powder, m.p. 194°-197°. Yield 119 g. (85.5%)
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04062869 |
| 出典データセット | uspto-grants-1977_12 |
| ORD ID | ord-934fc004b6e84a2bb6c09c3080607a5b |
| 出典メモ | uspto-grants-1977_12 |