関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 3-Butenenitrile | HCID 8009 | — |
| 反応物 | Dichloro(phenyl)silane | HCID 74207 | — |
| 触媒 | Platinum | HCID 23939 | — |
| 触媒 | Chloroplatinic acid | HCID 61859 | — |
| 生成物 | Butanenitrile, 4-(dichlorophenylsilyl)- | HCID 70649 | — |
反応手順
(γ-Cyanopropyl) phenyldichlorosilane was prepared by adding 67.1 grams (1.0 moles) of allylcyanide slowly to 177.1 grams (1.0 moles) of phenyldichlorosilane containing 10-4 moles of platinum as chloroplatinic acid at a temperature of 130° - 135° C. in a three-necked flask. After completion of the addition, the reaction mixture was heated at 120° C. for 16 hours. The pure (γ-cyanopropyl) phenyldichlorosilane was isolated by fractional distillation (b.p. 132° C./0.7 mm).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04063911 |
|---|
| 出典データセット | uspto-grants-1977_12 |
|---|
| ORD ID | ord-8063481af56440daac7e797b205c22f1 |
|---|
| 出典メモ | uspto-grants-1977_12 |
|---|
