Glycidyl methacrylate → Methacryloyloxyhydroxypropyl methyl octadecyl amine

HRID 461605

反応式

HRID 461605 の反応式
[CH3:1][NH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[C:21]([O:26]CC1OC1)(=[O:25])[C:22]([CH3:24])=[CH2:23]>CO>[C:21]([O:26][CH:3]([N:2]([CH2:23][CH2:22][CH2:21][OH:25])[CH3:1])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:25])[C:22]([CH3:24])=[CH2:23]

参加物

4

反応物 2

HCID 7837Glycidyl methacrylateHCID 75539N-Methyloctadecylamine

生成物 1

HCID 86733040Methacryloyloxyhydroxypropyl methyl octadecyl amine

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

Equimolar quantities of N-methyl-N-octadecyl amine and glycidyl methacrylate were reacted together in methanol to form methacryloyloxyhydroxypropyl methyl octadecyl amine. 14.3 grams of the resultant amine were dissolved in 20 grams of dimethyl formamide and 4.2 grams of dimethyl sulfate were added slowly with stirring. After 10 days' standing at 25° C, 9 grams of crystalline material was isolated, washed with ether, and dried. The sulfate band in the crystalline product was identified in the I.R. spectrum.

出典と根拠

ORDレコード
ord-3651fe7078604a7ca2e66b5fc20eea3b
出典データセット
uspto-grants-1977_12
特許番号
US04064091

関連ノート

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