1-Bromooctadecane → n-Octadecyl Dicyclohexylphosphinodithioate

HRID 461608

反応式

HRID 461608 の反応式
[CH:1]1([P:7]([CH:10]2[CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]2)([SH:9])=[S:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH2:16](Br)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33]>CC(C)=O>[CH:1]1([P:7]([CH:10]2[CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]2)([S:9][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH3:16])=[S:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1

参加物

4

反応物 2

HCID 82181-BromooctadecaneHCID 75641Phosphinodithioic acid, dicyclohexyl-

生成物 1

HCID 21391648n-Octadecyl Dicyclohexylphosphinodithioate収率 77.8%

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

To 14.0 g. (0.05 m.) of the ammonium salt of dicyclohexylphosphinodithioic acid in 250 mls. of acetone was added 16.67 g. (0.05 m.) of n-octadecylbromide and the mixture was refluxed for 15 hours. The precipitate was then separated by filtration and the filtrate was cooled to precipitate a crystalline solid. The crystalline material was filtered off and recrystallized from acetone to obtain 20 g. (77.8% yield) of product which melted at 67°-69° C.

後処理

  1. customThe precipitate was then separated by filtration
  2. temperaturethe filtrate was cooled
  3. customto precipitate a crystalline solid
  4. filtrationThe crystalline material was filtered off
  5. customrecrystallized from acetone
  6. customto obtain 20 g

出典と根拠

ORDレコード
ord-457ee94ea6cf49e78ef04328c9ee3c63
出典データセット
uspto-grants-1977_12
特許番号
US04064106

関連ノート

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