2,4-Dinitrobenzenesulfenyl chloride → Sulfide, bis(2,4-dinitrophenyl)

HRID 462114

反応式

HRID 462114 の反応式
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13]Cl)([O-:3])=[O:2]>C(O)(=O)C>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13][C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])([O-:3])=[O:2]

参加物

3

反応物 1

HCID 682512,4-Dinitrobenzenesulfenyl chloride

生成物 1

HCID 95960Sulfide, bis(2,4-dinitrophenyl)

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

To 1.38 g. of 3-butenyltributyltin was added 0.936 g. of 2,4-dinitrobenzene sulfenyl chloride in 20 ml. glacial acetic acid at steam bath temperature. The reaction mixture was warned on the steam bath for 20 minutes, poured into ice water and filtered. The mixture was extracted with pentane, dried and recrystallized from ethanol to yield cyclopropylcarbinyl 2,4-dinitrophenyl sulfide; m.p. 80°-81° C. Analysis for C and H confirmed the composition of the reaction product.

後処理

  1. filtrationfiltered
  2. extractionThe mixture was extracted with pentane
  3. customdried
  4. customrecrystallized from ethanol

出典と根拠

ORDレコード
ord-b81ce2ccbd9d4e35a163bfaf2c454ca3
出典データセット
uspto-grants-1977_12
特許番号
US04065480

関連ノート

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