4'-Chloroacetyl(acetanilide) → N,N-Dimethyl-N-(p-aminophenacyl)-N-3-aminopropylammonium chloride

HRID 462153

反応式

HRID 462153 の反応式
[CH3:1][N:2]([CH3:9])[CH2:3][CH2:4][CH2:5][NH:6]C=O.C([NH:13][C:14]1[CH:23]=[CH:22][C:17]([C:18](=[O:21])[CH2:19][Cl:20])=[CH:16][CH:15]=1)(=O)C>O>[Cl-:20].[CH3:1][N+:2]([CH3:9])([CH2:19][C:18]([C:17]1[CH:16]=[CH:15][C:14]([NH2:13])=[CH:23][CH:22]=1)=[O:21])[CH2:3][CH2:4][CH2:5][NH2:6]

参加物

4

反応物 2

HCID 88054'-Chloroacetyl(acetanilide)HCID 80020N-(3-(dimethylamino)propyl)formamide

生成物 1

HCID 86735871N,N-Dimethyl-N-(p-aminophenacyl)-N-3-aminopropylammonium chloride

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

To a stirred solution of 143.5 parts of N-(3-dimethylaminopropyl)formamide and 700 parts of water is added 249 parts of p-acetamidophenacyl cloride. The mixture is stirred at room temperature for 16 l hours and then at 60°-65° C. for 2 hours. Insoluble material is removed by filtration. The filtrate is combined with one-half its volume of concentrated hydrochloric acid (36% by weight) and the resulting solution is heated at the boil for two hours. The aqueous solution of N,N-dimethyl-N-(p-aminophenacyl)-N-3-aminopropylammonium chloride is used as such in the preparation of dyes.

後処理

  1. customInsoluble material is removed by filtration
  2. temperaturethe resulting solution is heated at the boil for two hours
  3. customsuch in the preparation of dyes

出典と根拠

ORDレコード
ord-fcbd66149d40432b977da38e3ff60b83
出典データセット
uspto-grants-1977_12
特許番号
US04065500

関連ノート

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