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Sodium Hydroxide → 3-Bromonaphthalene-1-carboxylic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | 5-Bromobenzo[de]isochromene-1,3-dione | HCID 3907491 | — |
| 触媒 | Mercuric oxide | HCID 30856 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 3-Bromonaphthalene-1-carboxylic acid | HCID 11708609 | — |
反応手順
To a mixture of 3-bromo-1,8-naphthalic anhydride (compound 74, 22.8 g, 82.4 mmol) and sodium hydroxide (13.2 g, 330 mmol) in water (500 mL) was added a solution of mercury(II) oxide (23.2 g, 107 mmol) in water (70 mL) and glacial acetic acid (24 mL). The reaction mixture was heated at reflux for 4 days and then cooled to room temperature. The resulting solid was filtered and dried in vacuo.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08541380B2 |
| 出典データセット | uspto-grants-2013_09 |
| ORD ID | ord-389f65625db94b4aa084f756bbdffb05 |
| 出典メモ | uspto-grants-2013_09 |