化工社化工社 化学情報印刷レポート · 研究参考用
Formaldehyde → 4,4-Di(hydroxymethyl)bicyclo(2.2.1)heptene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Formaldehyde | HCID 712 | — |
| 反応物 | Bicyclo(2.2.1)hept-5-ene-2-carboxaldehyde | HCID 95117 | — |
| 生成物 | 4,4-Di(hydroxymethyl)bicyclo(2.2.1)heptene | HCID 110917 | — |
反応手順
The synthesis of this chemical compound is depicted in Table I. The synthesis consists of the reaction of cyclopentene with acrolein to produce 5-norbornene-2-al. Reaction of 5-norbornene-2-al with formaldehyde results in the formation of 5-norbornene-2,2-dimethanol. Mild oxidation of the latter compound with dibutylstannic oxide yields the 3,9-bis(5'-norbornene-2'yl)-1,5,7,11-tetraoxaspiro[5.5]undecane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04515912 |
| 出典データセット | uspto-grants-1985_05 |
| ORD ID | ord-28176567ee1b4f57bad6f55744d701ad |
| 出典メモ | uspto-grants-1985_05 |