反応式
N=[C:2]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4](=[NH:11])[NH:3]1.[Br-:12].[CH3:13][C:14]1[S:15][C:16]2[CH:27]=[CH:26][CH:25]=[CH:24][C:17]=2[N+:18]=1[CH2:19][CH2:20][C:21]([OH:23])=[O:22]>O>[Br-:12].[NH:11]=[C:4]1[C:5]2[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=2)[C:2]([CH:13]=[C:14]2[NH+:18]([CH2:19][CH2:20][C:21]([OH:23])=[O:22])[C:17]3[CH:24]=[CH:25][CH:26]=[CH:27][C:16]=3[S:15]2)=[N:3]1参加物
4
実験手順
Three grams (0.02 mole) of 1,3-diiminoisoindoline was dissolved in 25 ml of warm water. Three grams (0.01 mole) of 2-methyl-3-carboxyethyl benzothiazolium bromide was added to the solution. A molar excess of 1,3-diiminoisoindoline was employed to avoid bis substitution. The solution was stirred and heated on a steam bath for 10 minutes. An orange solid separated from the solution. The solution was then cooled and the solid collected by filtration. The dye was redissolved in hot water with the aid of sodium hydroxide. The solution was filtered, and the filtrate was acidified with excess acetic acid to reprecipitate the dye. The dye was washed with water and methanol and vacuum dried at 70° C.
後処理
- temperatureheated on a steam bath for 10 minutes
- customAn orange solid separated from the solution
- temperatureThe solution was then cooled
- filtrationthe solid collected by filtration
- dissolutionThe dye was redissolved in hot water with the aid of sodium hydroxide
- filtrationThe solution was filtered
- washThe dye was washed with water and methanol and vacuum
- customdried at 70° C.
出典と根拠
- ORDレコード
- ord-f2668e6da42a42bf9ae7bc67c3ff6a69
- 出典データセット
- uspto-grants-1985_05
- 特許番号
- US04515955
関連ノート
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